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・ Potassium feldspar
・ Potassium ferrate
・ Potassium ferricyanide
・ Potassium ferrioxalate
・ Potassium ferrocyanide
・ Potassium fluoride
・ Potassium fluoride on alumina
・ Potassium formate
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・ Potassium hexachloroplatinate
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・ Potassium hexafluorocuprate(III)
Potassium hexafluoronickelate(IV)
・ Potassium hexafluorophosphate
・ Potassium humate
・ Potassium hydride
・ Potassium hydrogen phthalate
・ Potassium hydrogenacetylenedicarboxylate
・ Potassium hydrogenoxalate
・ Potassium hydrosulfide
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・ Potassium in biology
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・ Potassium iodide
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Potassium hexafluoronickelate(IV) : ウィキペディア英語版
Potassium hexafluoronickelate(IV)

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Potassium hexafluoronickelate(IV) is an inorganic compound with the chemical formula . It can be produced through the reaction of potassium fluoride, nickel dichloride, and fluorine.
It reacts violently with water, releasing oxygen. It dissolves in anhydrous hydrogen fluoride to produce a light-red solution. Potassium hexafluoronickelate(IV) decomposes at 350 °C, forming potassium hexafluoronickelate(III), nickel(II) fluoride, and fluorine:
:\rm \ 3 K_2NiF_6 \xrightarrow 2 K_3NiF_6 + NiF_2 + F_2
Potassium hexafluoronickelate is a very strong oxidant. It can turn chlorine pentafluoride and bromine pentafluoride into and , respectively:
:\rm \ K_2NiF_6 + 5 AsF_5 + XF_5 \xrightarrow XF_6AsF_6 + Ni(AsF_6)_2 + 2KAsF_6
:( X = Cl or Br , -60 °C , aHF = anhydrous hydrogen fluoride )
== References ==



抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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